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• W2034267190 abstract "Temperature-programmed desorption is shown to be an effective method to measure the volume of non-zeolitic pores in a MFI membrane. A molecule that was too large to adsorb into the MFI pores at room temperature and the experimental time scale, 2,2-dimethylbutane, was adsorbed in the non-zeolitic pores, and its liquid density was used to estimate their pore volume. When n-hexane or n-octane adsorbed in the MFI pores, the non-zeolitic pore volume decreased by 55%, whereas benzene adsorbed in the MFI pores had no effect. The non-zeolitic pore volume decreased because n-hexane and n-octane swell the MFI crystals of the membrane and decrease the non-zeolitic pore size (the space between the MFI crystals), but benzene does not." @default.
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• W2034267190 date "2008-08-01" @default.
• W2034267190 modified "2023-09-27" @default.
• W2034267190 title "Characterizing non-zeolitic pore volume in zeolite membranes by temperature-programmed desorption" @default.
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• W2034267190 doi "https://doi.org/10.1016/j.micromeso.2007.11.021" @default.
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