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- W2034267613 abstract "Proton affinities of a series of triphenyl Group Va compounds have been determined by bracketing using reactant ion monitoring: (C6H5)3N = 904 ± 8 kJ mol−1, (C6H5)3P = 968 ± 5 kJ mol−1, (C6H5)3As = 904 ± 8 kJ mol−1 and (C6H5)3Sb = 846 ± 8 kJ mol−1. The large difference in substituent effect of phenyl for hydrogen between As or P and N may result from overlap of the 2p orbitals of N with the sp2 orbitals on the ring carbons and lack of overlap for P or As. Proton affinities of phenylalkylphosphine oxides are essentially the same, 904 ± 8 kJ mol−1, independent of alkyl group." @default.
- W2034267613 created "2016-06-24" @default.
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- W2034267613 date "1986-01-01" @default.
- W2034267613 modified "2023-09-23" @default.
- W2034267613 title "Proton affinities by reactant ion monitoring: Triphenyl group Va compounds" @default.
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- W2034267613 doi "https://doi.org/10.1002/oms.1210210109" @default.
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