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- W2034268078 abstract "Nonconcerted Cope-Rearrangement? 1,2,6,7-Cyclodecatetraene Thermolysis From the pressure and oxygen dependence of the trapping rate a two-step mechanism for the Cope rearrangement of the title compound is deduced, its energy profile established, and the heat of formation of the intermediate diradical 3 determined. In contrast to the meso compound the rearrangement of the rac isomer proceeds by two competing processes, a concerted and a nonconcerted pathway. The different behavior of the meso and rac compound can be correlated to the boat and chair geometry of the respective transition states." @default.
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- W2034268078 date "1992-03-01" @default.
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- W2034268078 title "Nichtkonzertierte Cope‐Umlagerung? 1,2,6,7‐Cyclodecatetraen‐Thermolyse" @default.
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- W2034268078 doi "https://doi.org/10.1002/cber.19921250330" @default.
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