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• W2034268977 abstract "Abstract Uniform Li 3 VO 4 film was successfully grown on porous Ni foam, which shows good electrochemical performance as anode for Li-ion battery due to the improved reaction kinetics. The as-prepared Li 3 VO 4 /Ni electrode can deliver discharge and charge capacity of 379 and 378 mAh g −1 after 100 cycles at a charge/discharge rate of 0.3 C. After various charge/discharge rates from 0.4 to 15 C, the discharge capacity of the Li 3 VO 4 /Ni electrode can restore to 404 mAh g −1 when lowering the charge/discharge rate to 0.4 C. The reaction kinetics of the Li 3 VO 4 /Ni electrode was studied by cyclic voltammetry (CV) measurement at various scan rate and electrochemical impedance spectroscopy (EIS). Linear dependence between anodic/cathodic peak currents and the square root of scan rate suggests a lithium ion diffusion controlled mechanism of Li 3 VO 4 /Ni electrode in charge/discharge process, and the symmetrical slope of the two straight lines indicates a highly reversible lithiation/delithiation process. EIS measurements of the Li 3 VO 4 /Ni electrode show low and stable contact and charge-transfer resistances in cycling, suggesting highly stable charge transfer process and Li-ion diffusion coefficient." @default.
• W2034268977 created "2016-06-24" @default.
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• W2034268977 date "2014-06-01" @default.
• W2034268977 modified "2023-10-18" @default.
• W2034268977 title "The fabrication of Li3VO4/Ni composite material and its electrochemical performance as anode for Li-ion battery" @default.
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• W2034268977 doi "https://doi.org/10.1016/j.electacta.2014.03.120" @default.
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