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• W2034271485 abstract "Abstract State‐of‐the‐art ab initio studies demonstrate that the reaction Pd + + CH 3 I → PdCH 2 I + + H . is endothermic by ca. 20 kcal/mol, which translates into a bond dissociation energy ( BDE ) of ca. 83 kcal/mol for the Pd + CH 2 I bond. This figure is in agreement with an experimental bracket of 68 kcal/mol < BDE (Pd + CH 2 I) < 92 kcal/mol. Based on these findings, the previously studied Pd + /CH 3 I system was re‐investigated, and double‐resonance experiments demonstrate that the formation of PdCH 2 I + occurs stepwise via PdCH as a reactive intermediate. Further, ion/molecule reactions of PdCH 2 I + with unsaturated hydrocarbons are studied, which reveal the formation of carbon–carbon bonds in the gas phase." @default.
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• W2034271485 date "1996-06-26" @default.
• W2034271485 modified "2023-10-16" @default.
• W2034271485 title "Theory-enforced Re-investigation of the Origin of the Large Metal-Carbon Bond Strength in PdCH₂I⁺and its reactions with unsaturated hydrocarbons" @default.
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• W2034271485 doi "https://doi.org/10.1002/hlca.19960790419" @default.
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