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- W2034272642 abstract "Abstract The thermal dehydrochlorination CF 2 ClCH 3 → CF 2 CH 2 + HCl has been studied in a static system between 637 and 758 K. It is a homogeneous, molecular first‐order reaction and its rate constant is given by This reaction has also been studied in the presence of CCl 4 and mixtures of CCl 4 and HCl between 585 and 662 K. It is then accelerated and the initial rate increase is given by with log 10 ( k ′, L ½ /mol ½ · s) = −(41,650 ± 180)/4.576 T + (10.84 ± 0.06) and log 10 k ″ = (7900 ± 180)/4.576 T − (0.59 ± 0.06). A radical chain mechanism is shown to be consistent with these latter results." @default.
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- W2034272642 date "1985-05-01" @default.
- W2034272642 modified "2023-10-11" @default.
- W2034272642 title "Pyrolysis of 1-chloro-1,1-difluoroethane in the absence and in the presence of CCl4 and mixtures of CCl4 + HCl" @default.
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- W2034272642 doi "https://doi.org/10.1002/kin.550170204" @default.
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