FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034275310> ?p ?o ?g. }

• W2034275310 endingPage "111" @default.
• W2034275310 startingPage "107" @default.
• W2034275310 abstract "Abstract Working electrodes made out of pyrolytic graphite, glassy carbon, platinum and cadmium were compared for the electrochemical generation of volatile lead species. The same electrolytic cell, using each of the different working electrodes was coupled to an atomic absorption spectrometer and the experimental conditions were optimized in each case, using a univariate approach, to produce the maximum possible amount of volatile lead species. The experiments were focused on the variation of cathode hydrogen overvoltage by the application of a constant current during analysis. Under optimum conditions the performance of the electrochemical hydride generator cell should depend on the cathode material selected due to the different hydrogen overpotential of each material. The lead absorbance signal was taken as a measure of the efficiency of volatile lead species production. Best results were obtained using the Cd cathode, due to its relatively highest hydrogen overpotential, a carrier gas (Ar) flow rate of 55 mL min − 1 an electrolytic current of 0.8 A and a catholyte (HCl) concentration 0.05 mol L − 1 . The analytical figures of merit of the method using the Cd electrode were evaluated and the susceptibility of the method to interferences was assessed by its application to the determination of trace amounts of lead in the presence of the most significant interferents. The calibration curve was linear between 0.5 and 15 μg L − 1 Pb. Detection limits and characteristic mass values were 0.21 μg L − 1 and 0.26 μg L − 1 respectively. A bovine liver standard reference material and a spiked urine sample were analyzed to check accuracy." @default.
• W2034275310 created "2016-06-24" @default.
• W2034275310 creator A5001980870 @default.
• W2034275310 creator A5010423326 @default.
• W2034275310 creator A5078392397 @default.
• W2034275310 creator A5084707319 @default.
• W2034275310 date "2012-05-01" @default.
• W2034275310 modified "2023-10-18" @default.
• W2034275310 title "Electrochemical generation of volatile lead species using a cadmium cathode: Comparison with graphite, glassy carbon and platinum cathodes" @default.
• W2034275310 cites W1534900050 @default.
• W2034275310 cites W1964666844 @default.
• W2034275310 cites W1965183391 @default.
• W2034275310 cites W1967941838 @default.
• W2034275310 cites W1970008871 @default.
• W2034275310 cites W1971053043 @default.
• W2034275310 cites W1981261704 @default.
• W2034275310 cites W1984360201 @default.
• W2034275310 cites W1986862194 @default.
• W2034275310 cites W1988965539 @default.
• W2034275310 cites W1992752034 @default.
• W2034275310 cites W2008943302 @default.
• W2034275310 cites W2010025903 @default.
• W2034275310 cites W2015300262 @default.
• W2034275310 cites W2018336526 @default.
• W2034275310 cites W2031132971 @default.
• W2034275310 cites W2034541079 @default.
• W2034275310 cites W2047925601 @default.
• W2034275310 cites W2049624443 @default.
• W2034275310 cites W2052915059 @default.
• W2034275310 cites W2078425042 @default.
• W2034275310 cites W2085541573 @default.
• W2034275310 cites W2090892268 @default.
• W2034275310 cites W2135350486 @default.
• W2034275310 cites W2137061838 @default.
• W2034275310 cites W2138540125 @default.
• W2034275310 cites W2161118610 @default.
• W2034275310 doi "https://doi.org/10.1016/j.sab.2012.03.009" @default.
• W2034275310 hasPublicationYear "2012" @default.
• W2034275310 type Work @default.
• W2034275310 sameAs 2034275310 @default.
• W2034275310 citedByCount "16" @default.
• W2034275310 countsByYear W20342753102012 @default.
• W2034275310 countsByYear W20342753102013 @default.
• W2034275310 countsByYear W20342753102015 @default.
• W2034275310 countsByYear W20342753102016 @default.
• W2034275310 countsByYear W20342753102017 @default.
• W2034275310 countsByYear W20342753102018 @default.
• W2034275310 countsByYear W20342753102021 @default.
• W2034275310 countsByYear W20342753102022 @default.
• W2034275310 crossrefType "journal-article" @default.
• W2034275310 hasAuthorship W2034275310A5001980870 @default.
• W2034275310 hasAuthorship W2034275310A5010423326 @default.
• W2034275310 hasAuthorship W2034275310A5078392397 @default.
• W2034275310 hasAuthorship W2034275310A5084707319 @default.
• W2034275310 hasConcept C104779481 @default.
• W2034275310 hasConcept C114793014 @default.
• W2034275310 hasConcept C127313418 @default.
• W2034275310 hasConcept C127413603 @default.
• W2034275310 hasConcept C140205800 @default.
• W2034275310 hasConcept C147789679 @default.
• W2034275310 hasConcept C159985019 @default.
• W2034275310 hasConcept C161790260 @default.
• W2034275310 hasConcept C17525397 @default.
• W2034275310 hasConcept C178790620 @default.
• W2034275310 hasConcept C179104552 @default.
• W2034275310 hasConcept C185592680 @default.
• W2034275310 hasConcept C191897082 @default.
• W2034275310 hasConcept C192562407 @default.
• W2034275310 hasConcept C2776422427 @default.
• W2034275310 hasConcept C2777093003 @default.
• W2034275310 hasConcept C2777869211 @default.
• W2034275310 hasConcept C2779698641 @default.
• W2034275310 hasConcept C42360764 @default.
• W2034275310 hasConcept C49110097 @default.
• W2034275310 hasConcept C518104683 @default.
• W2034275310 hasConcept C52859227 @default.
• W2034275310 hasConcept C544657597 @default.
• W2034275310 hasConceptScore W2034275310C104779481 @default.
• W2034275310 hasConceptScore W2034275310C114793014 @default.
• W2034275310 hasConceptScore W2034275310C127313418 @default.
• W2034275310 hasConceptScore W2034275310C127413603 @default.
• W2034275310 hasConceptScore W2034275310C140205800 @default.
• W2034275310 hasConceptScore W2034275310C147789679 @default.
• W2034275310 hasConceptScore W2034275310C159985019 @default.
• W2034275310 hasConceptScore W2034275310C161790260 @default.
• W2034275310 hasConceptScore W2034275310C17525397 @default.
• W2034275310 hasConceptScore W2034275310C178790620 @default.
• W2034275310 hasConceptScore W2034275310C179104552 @default.
• W2034275310 hasConceptScore W2034275310C185592680 @default.
• W2034275310 hasConceptScore W2034275310C191897082 @default.
• W2034275310 hasConceptScore W2034275310C192562407 @default.
• W2034275310 hasConceptScore W2034275310C2776422427 @default.
• W2034275310 hasConceptScore W2034275310C2777093003 @default.
• W2034275310 hasConceptScore W2034275310C2777869211 @default.
• W2034275310 hasConceptScore W2034275310C2779698641 @default.
• W2034275310 hasConceptScore W2034275310C42360764 @default.
• W2034275310 hasConceptScore W2034275310C49110097 @default.
• W2034275310 hasConceptScore W2034275310C518104683 @default.

• next