Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034275318> ?p ?o ?g. }
Showing items 1 to 62 of
62
with 100 items per page.
- W2034275318 endingPage "1422" @default.
- W2034275318 startingPage "1422" @default.
- W2034275318 abstract "The Claisen rearrangement of a series of allyl tocopheryl ethers has been studied kinetically in order to examine the possibility that the pronounced Mills–Nixon effect in 6-chromanols can be attributed to a significant degree of bond fixation in these compounds. The rearrangements of allyl tocyl ether and allyl δ-tocopheryl ether were similar and gave the 5-allyltocopherol predominantly in each case. There were kinetic differences in the rearrangements of the β-tocopheryl and γ-tocopheryl ethers, and a difference of 2·6 kcal./mole in their activation energies, which suggests that a mild degree of bond fixation might exist in these compounds. The pyrolysis of allyl α-tocopheryl ether at 192° yields α-tocopherol rapidly and in good yield." @default.
- W2034275318 created "2016-06-24" @default.
- W2034275318 creator A5036377113 @default.
- W2034275318 creator A5089993018 @default.
- W2034275318 creator A5002529465 @default.
- W2034275318 date "1966-01-01" @default.
- W2034275318 modified "2023-10-09" @default.
- W2034275318 title "Bond stabilisation in tocopherols. Part I. The Claisen rearrangement of allyl tocopheryl ethers" @default.
- W2034275318 doi "https://doi.org/10.1039/j39660001422" @default.
- W2034275318 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/5949782" @default.
- W2034275318 hasPublicationYear "1966" @default.
- W2034275318 type Work @default.
- W2034275318 sameAs 2034275318 @default.
- W2034275318 citedByCount "3" @default.
- W2034275318 crossrefType "journal-article" @default.
- W2034275318 hasAuthorship W2034275318A5002529465 @default.
- W2034275318 hasAuthorship W2034275318A5036377113 @default.
- W2034275318 hasAuthorship W2034275318A5089993018 @default.
- W2034275318 hasConcept C134121241 @default.
- W2034275318 hasConcept C155647269 @default.
- W2034275318 hasConcept C178790620 @default.
- W2034275318 hasConcept C185592680 @default.
- W2034275318 hasConcept C191897082 @default.
- W2034275318 hasConcept C192562407 @default.
- W2034275318 hasConcept C2777551382 @default.
- W2034275318 hasConcept C2778004101 @default.
- W2034275318 hasConcept C2780407432 @default.
- W2034275318 hasConcept C2780567667 @default.
- W2034275318 hasConcept C2781449162 @default.
- W2034275318 hasConcept C68381374 @default.
- W2034275318 hasConceptScore W2034275318C134121241 @default.
- W2034275318 hasConceptScore W2034275318C155647269 @default.
- W2034275318 hasConceptScore W2034275318C178790620 @default.
- W2034275318 hasConceptScore W2034275318C185592680 @default.
- W2034275318 hasConceptScore W2034275318C191897082 @default.
- W2034275318 hasConceptScore W2034275318C192562407 @default.
- W2034275318 hasConceptScore W2034275318C2777551382 @default.
- W2034275318 hasConceptScore W2034275318C2778004101 @default.
- W2034275318 hasConceptScore W2034275318C2780407432 @default.
- W2034275318 hasConceptScore W2034275318C2780567667 @default.
- W2034275318 hasConceptScore W2034275318C2781449162 @default.
- W2034275318 hasConceptScore W2034275318C68381374 @default.
- W2034275318 hasLocation W20342753181 @default.
- W2034275318 hasLocation W20342753182 @default.
- W2034275318 hasOpenAccess W2034275318 @default.
- W2034275318 hasPrimaryLocation W20342753181 @default.
- W2034275318 hasRelatedWork W1974346060 @default.
- W2034275318 hasRelatedWork W1993584118 @default.
- W2034275318 hasRelatedWork W1993962622 @default.
- W2034275318 hasRelatedWork W2015003182 @default.
- W2034275318 hasRelatedWork W2023890117 @default.
- W2034275318 hasRelatedWork W2300603869 @default.
- W2034275318 hasRelatedWork W2758716131 @default.
- W2034275318 hasRelatedWork W2949435949 @default.
- W2034275318 hasRelatedWork W2951306579 @default.
- W2034275318 hasRelatedWork W4239500656 @default.
- W2034275318 isParatext "false" @default.
- W2034275318 isRetracted "false" @default.
- W2034275318 magId "2034275318" @default.
- W2034275318 workType "article" @default.