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• W2034280435 abstract "Binary complexes of the glycinehydroxamic acid (GX) with copper(II) (GX-CuII), as well as their interaction with vitamin B6 compounds [pyridoxol (P), pyridoxal (PL) and pyridoxamine (PM)] were studied by pH-metric, differential pulse polarography (DPP), and electron paramagnetic resonance techniques at the ionic strength of 0.15 M NaCl and at 25°C. The formation constants of the binary and ternary species were determined using the SUPERQUAD program. The three ternary systems do not show the same stoichiometries of the different species, in addition, PL interacts with GX to form Schiff bases at pH > 4.5. Comparative studies of the DPP of the binary and ternary systems of CuII revealed that CuII is more stabilized toward reduction in the presence of PM than in presence of GX at pH > 6.0; in addition the redox behaviour of CuII in the presence of PM is similar to that of the GX-Pm-CuII ternary system. On the other hand, the DPP of the ternary systems GX-P (or PL)-CuII are similar to those of GX-CuII binary system at different pH values. The nuclear spin-electron spin coupling of CuII in these systems is discussed." @default.
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• W2034280435 date "1995-07-01" @default.
• W2034280435 modified "2023-09-23" @default.
• W2034280435 title "Complexes of vitamin B6—part XXII. The interaction of vitamin B6 compounds with CUII-glycinehydroxamic acid binary system" @default.
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• W2034280435 doi "https://doi.org/10.1016/0277-5387(94)00456-o" @default.
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