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- W2034283524 abstract "Abstract The manipulation of the properties of cycloaliphatic epoxy resins by systematical variations of the molecular structure is demonstrated. Specifically, four cycloaliphatic epoxy resins with silicon‐center linked via methyl, phenyl, and epoxy groups of different number were synthesized. The cured epoxides had remarkably changed crosslinking density from 0.45 × 10 −3 to 9.64 × 10 −3 mol · cm −3 , glass transition temperature from 133 to 237 °C, and considerably decreased thermal expansion coefficient from 6.44 × 10 −5 to 4.83 × 10 −5 K −1 . It was proved that the higher crosslinking density was related to more opened segments by wide‐angle X‐ray diffraction. The physical properties of cured products and their correlations with the chemical structures were investigated in detail. magnified image" @default.
- W2034283524 created "2016-06-24" @default.
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- W2034283524 date "2011-02-25" @default.
- W2034283524 modified "2023-10-18" @default.
- W2034283524 title "Silicon-Containing Cycloaliphatic Epoxy Resins with Systematically Varied Functionalities: Synthesis and Structure/Property Relationships" @default.
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- W2034283524 doi "https://doi.org/10.1002/macp.201000779" @default.
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