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- W2034283657 abstract "The oxide oxygen of α-Bi2Mo3O12was exchanged via olefin oxidation using18O2. Band shifts in the Raman spectra of the catalyst were examined. In the oxidation of propene and trans-but-2-ene, the bands at 865 and 845 cm−1of α-Bi2Mo3O12were shifted preferentially. Oxygen insertion apparently takes place at the vacancies on Mo–O tetrahedra associated with these bands. Four deuterated acrolein species obtained from the oxidation of cis-CHD=CD–CH3over α-Bi2Mo3O12and MoO3catalysts were examined by microwave spectroscopy. The products exhibited an isotope effect for the second hydrogen abstraction. This is consistent with a fast π-allyl to σ-allyl equilibration process over γ-Bi2MoO6as reported previously. These results were discussed with focus on the allyl intermediate associated with the catalyst and the oxide tetrahedra. In particular, specific Mo–O bonds in the α1and α2tetrahedra are identified as involved in the oxidation process." @default.
- W2034283657 created "2016-06-24" @default.
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- W2034283657 date "1998-04-01" @default.
- W2034283657 modified "2023-10-14" @default.
- W2034283657 title "Tracer Studies of Olefin Oxidation over an α-Bi2Mo3O12Catalyst Using Laser Raman and Microwave Spectroscopy" @default.
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- W2034283657 doi "https://doi.org/10.1006/jcat.1998.2006" @default.
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