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- W2034285594 abstract "Electron beam irradiation of methane containing small amounts of carbon monoxide in a flow system at atmospheric pressure produced acetic and propionic acids in considerable yields. Propionic acid was formed in preference to acetic acid, especially at small molar ratios, [CO]/[CH4]. These acids were though to be formed via Koch-Haaf reactions CH3++CO→CH3CO+→H2OCH3COOH2+C2H5++CO→C2H5CO+→H2OC2H5COOH2+ The decrease in G(H2) observed by the addition of CO to methane was interpreted on the basis of the following reaction H+CO→k2HCO The estimated values of k2 were close to the reported value." @default.
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- W2034285594 date "1981-01-01" @default.
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- W2034285594 title "Radiolysis of methane containing small amounts of carbon monoxide—formation of organic acids" @default.
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- W2034285594 doi "https://doi.org/10.1016/0146-5724(81)90333-2" @default.
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