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- W2034288047 abstract "The photoexcited triplet state of C60 in fluid toluene solution was investigated by pulsed-EPR spectroscopy in a temperature range T = 200–300 K. The time evolution of the triplet EPR signal is found to be determined by the spin-lattice relaxation time T1 and the triplet decay. In the presence of the electron donor end-capped quaterthiophene the C60-triplet decay is quenched by electron transfer reaction. The temperature dependence of the triplet quenching rate kq suggests the formation of an exciplex intermediate. Moreover we observe the formation of the C60-radical anion following electron transfer. The kinetics and polarization of the C60- EPR signal are discussed." @default.
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- W2034288047 date "1994-07-01" @default.
- W2034288047 modified "2023-10-16" @default.
- W2034288047 title "Pulsed-EPR on the photoexcited triplet state of C60 in fluid solution: electron transfer from end-capped quaterthiophene and C60-radical anion formation" @default.
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- W2034288047 doi "https://doi.org/10.1016/0301-0104(94)00115-4" @default.
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