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• W2034291507 abstract "Nuclear magnetic resonance data for a series of 2′-halogeno and 3′-halogeno pyrimidine nucleosides are presented. Using a combination of proton–proton and proton–fluorine couplings vs. dihedral angle values 2′-deoxy-2′-fluorouridine is proposed to have an envelope conformation with C–3′ endo, and 1-(3-deoxy-3-fluoro-β-D-arabinofuranosyl)uracil proposed to have a twist conformation with O-ring endo and C–1′ exo. Correlations between substituent electronegativity and both vicinal coupling constants and internal chemical shifts are discussed.Syntheses of several new 2′-halogeno and 3′-halogeno nucleosides are described." @default.
• W2034291507 created "2016-06-24" @default.
• W2034291507 creator A5029635607 @default.
• W2034291507 creator A5069908505 @default.
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• W2034291507 date "1968-04-01" @default.
• W2034291507 modified "2023-09-26" @default.
• W2034291507 title "Nucleosides. XLIX. Nuclear magnetic resonance studies of 2′-and 3′-halogeno nucleosides. The conformations of 2′-deoxy-2′-fluorouridine and 3′-deoxy-3′-fluoro-β-D-arabinofuranosyluracil" @default.
• W2034291507 doi "https://doi.org/10.1139/v68-188" @default.
• W2034291507 hasPublicationYear "1968" @default.
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