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• W2034291662 abstract "Enzymatic polymerization of phenol catalyzed by horseradish peroxidase (HRP) has been carried out in aqueous micelle system using sodium dodecyl benzene sulfonate (SDBS) as a surfactant. The addition of SDBS to buffer greatly enhances the polymer yield. With a usage of SDBS over 0.4 g for 5 mmol of phenol monomer, the polymer could be obtained almost quantitatively. The number-molecular weight of the THF-soluble part determined by GPC is increased from 1100 to 2000 with increasing the dosage of SDBS. The phenol polymerization maintains high yields in aqueous micelle system over a wide pH range from 4 to 10. The activity of enzyme in buffer is so high that the phenol polymerization in aqueous micelle system could be completed only in 2 h with high yield. The resulting polymer is a kind of powdery material, which is partly soluble in DMF, DMSO and THF. IR analysis showed that the polymer structure contained a mixture of phenylene and oxyphenylene units. From TG analysis, the polymer was found to possess high thermal stability." @default.
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• W2034291662 date "2012-03-01" @default.
• W2034291662 modified "2023-10-16" @default.
• W2034291662 title "Enzymatic polymerization of phenol catalyzed by horseradish peroxidase in aqueous micelle system" @default.
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• W2034291662 doi "https://doi.org/10.1016/j.eurpolymj.2011.12.011" @default.
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