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- W2034293874 abstract "A series of metallosilicates (transition metal elements—TME) MCM-41 (TME=Fe, Cu, Nb, V, Mo) mesoporous molecular sieves with variable Si/TME ratios have been synthesized and characterised by low temperature N2 adsorption/desorption, XRD, XPS, H2-TPR, FTIR combined with NO+NO2 adsorption, diffuse reflectance UV–Vis spectroscopy, and ESR study. All the materials exhibit hexagonal arrangement of uniform mesopores (with exception of CuMCM-41). Defect holes amid the nanochanels besides well-ordered mesopores characterise mainly Fe-containing materials, in which the highest TME loading was reached. Similar but smaller defects take place in NbMCM-41. The amount of TME included into MCM-41 structure under the preparation conditions used in this work changes in the order: Fe>Nb>Cu≫V≫Mo. This sequence is not related to the oxidation state of metals which was estimated in calcined materials as Fe3+, Nb5+, Cu2+, V5+, Mo6+. It does not also correlate with cation sizes in a simple way. The possibility of forming tetrahedral coordination seems to limit the TME incorporation into the MCM-41 skeleton if free metal cations are used in the gel (Cu2+, Fe3+, Nb5+). Al in the gel makes the isomorphously substitution of silicon by copper easier, but part of Cu occupies extra framework cationic positions in the final material." @default.
- W2034293874 created "2016-06-24" @default.
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- W2034293874 date "2004-03-01" @default.
- W2034293874 modified "2023-09-29" @default.
- W2034293874 title "Template synthesis and characterisation of MCM-41 mesoporous molecular sieves containing various transition metal elements—TME (Cu, Fe, Nb, V, Mo)" @default.
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- W2034293874 doi "https://doi.org/10.1016/j.jpcs.2003.10.048" @default.
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