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- W2034294178 abstract "Broad line NMR and spin-lattice relaxation times T1 have been used to study glass transition phenomena in isotactic polypropylene modified and blended with an ethylene aminoalkylacrylate copolymer. By means of decomposition of spectra into elementary components corresponding to the chains with different mobility a softening due to the polymer modifier was observed. The modification results in an increase of fractions of amorphous and intermediate chains, respectively, gives rise to the enhancement of the chain mobility in amorphous regions, but the higher amount of the polymer modifier, which was used in the range up to 15 wt%, the lower chain mobility in intermediate regions was found out. From the temperature dependences of the spin-lattice relaxation times T1 measured over the temperature range 290–430 K, a broadening of correlation time distribution on the side of the shorter correlation times has been found out to be and it was ascribed to overlapping of relaxation processes in amorphous regions. The sample containing the highest amount of the polymer modifier, in contrast to others, was shown to blend not only on the molecular level but also on the overmolecular." @default.
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- W2034294178 date "1996-03-01" @default.
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- W2034294178 title "NMR Study of β Relaxation in Modified and Blended Isotactic Polypropylene" @default.
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- W2034294178 doi "https://doi.org/10.1295/polymj.28.232" @default.
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