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- W2034294987 abstract "A highly efficient trifluoromethanesulfonic acid-mediated rearrangement of the benzoylaminomethylthio group of 3-benzoylaminomethylthioindoles (7a–e) to position 2 of the indole ring was developed. Thus, 2-benzoylaminomethylthioindoles (9a–e) were obtained in good yields and were involved as key intermediates in the synthesis of the new γ-carboline analogue ring system: 2,9-dihydro-4-aryl-1,3-thiazino[6,5-b]indole derivatives (11a–e). The target thiazinoindoles (11a–e) were prepared via 2-thiobenzoylaminomethylindoles (10a–e) in modified Bischler–Napieralski reactions." @default.
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- W2034294987 date "2009-02-01" @default.
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- W2034294987 title "An expeditious synthesis for γ-carboline analogue 4-aryl-1,3-thiazino[6,5-b]indole derivatives via the trifluoromethanesulfonic acid-promoted isomerization of 3-amidomethylthioindole intermediates to 2-indolyl sulfides" @default.
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- W2034294987 doi "https://doi.org/10.1016/j.tet.2008.11.099" @default.
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