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- W2034298345 abstract "The phase state and phase transitions in melts and solutions of polycapramide (PCA) in caprolactam were studied by means of viscosimetry, optical interferometry, and polarization microscopy. It has been shown that the orientation of macromolecules of PCA in the flow zone results in the expansion of the area of immiscibility in the phase diagram. The isothermal crystallization was traced by the change of the length of the induction period by means of viscosimetry measurements. The dependence of the rate of isothermal crystallization on the rate of shear deformation is quite marked. The decrease of the rate of crystallization at high rates of shear is believed to be associated with the destruction of critical-size nuclei in a high velocity gradient stream." @default.
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- W2034298345 date "1981-10-01" @default.
- W2034298345 modified "2023-10-17" @default.
- W2034298345 title "The effect of deformation on the phase separation in the polycapramide-caprolactam system" @default.
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- W2034298345 doi "https://doi.org/10.1016/0032-3861(81)90240-8" @default.
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