Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034301438> ?p ?o ?g. }
- W2034301438 endingPage "2152" @default.
- W2034301438 startingPage "2142" @default.
- W2034301438 abstract "Abstract p-Cymene complexes MCl2(η6-p-cymene)L [M = Ru, Os; L = P(OEt)3, PPh(OEt)2, (CH3)3CNC] were prepared by allowing [MCl(μ-Cl)(η6-p-cymene)]2 to react with phosphites or tert-butyl isocyanide. Treatment of MCl2(η6-p-cymene)L complexes with 1,3-ArN NN(H)Ar triazene and an excess of NEt3 gave the cationic triazenide derivatives [M(η2-1,3-ArNNNAr)(η6-p-cymene)L]BPh4 (Ar = Ph, p-tolyl). Neutral triazenide complexes MCl(η2-1,3-ArNNNAr)(η6-p-cymene) (M = Ru, Os) were also prepared by allowing [MCl(μ-Cl)(η6-p-cymene)]2 to react with 1,3-diaryltriazene in the presence of triethylamine. p-Cymene complexes MCl2(η6-p-cymene)L reacted with equimolar amounts of 1,3-ArN NN(H)Ar triazene to give both triazenide complexes [M(η2-1,3-ArNNNAr)(η6-p-cymene)L]BPh4 and amine derivatives [MCl(ArNH2)(η6-p-cymene)L]BPh4. A reaction path for the formation of the amine complex is also reported. The complexes were characterised by spectroscopy and X-ray crystallography of RuCl2(η6-p-cymene)[PPh(OEt)2] and [Ru(η2-1,3-p-tolyl-NNN-p-tolyl)(η6-p-cymene){CNC(CH3)3}]BPh4. Selected triazenide complexes were studied as catalysts in the hydrogenation of 2-cyclohexen-1-one and cinnamaldehyde." @default.
- W2034301438 created "2016-06-24" @default.
- W2034301438 creator A5024372989 @default.
- W2034301438 creator A5046582495 @default.
- W2034301438 creator A5059343350 @default.
- W2034301438 creator A5061193642 @default.
- W2034301438 date "2010-08-01" @default.
- W2034301438 modified "2023-10-04" @default.
- W2034301438 title "Preparation and reactivity of p-cymene complexes of ruthenium and osmium incorporating 1,3-triazenide ligands" @default.
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