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• W2034302551 abstract "Exploiting nanoscopically tunable composite gold--alkanethiol--ionic-liquid/ferrocene self-assembled systems with tunable electron transfer distance, we discovered in the case of thinner alkanethiol films a thermally activated electron transfer pattern totally controlled by the viscosity-related slow relaxation mode(s) of the ionic liquid acting as the reactant's fluctuating environment. This pattern manifested through the activation enthalpy and volume parameters that are identical to those for viscous flow was explained in terms of the extreme adiabatic mechanism with a vanishing Marcus barrier (via the exponential Franck-Condon-like term approaching unity)." @default.
• W2034302551 created "2016-06-24" @default.
• W2034302551 creator A5063569815 @default.
• W2034302551 creator A5066913578 @default.
• W2034302551 creator A5080879830 @default.
• W2034302551 date "2009-12-04" @default.
• W2034302551 modified "2023-09-27" @default.
• W2034302551 title "Unusual mechanism for the short-range electron transfer within gold–alkanethiol–ionic-liquid films of subnanometer thickness" @default.
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• W2034302551 doi "https://doi.org/10.1103/physreve.80.065101" @default.
• W2034302551 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20365213" @default.
• W2034302551 hasPublicationYear "2009" @default.
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