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- W2034303887 abstract "The RuCl3 catalysed epoxidation of olefins gave more than 10% of epoxide. Pyridine addition increased the yield and selectivity of the epoxide. Epoxidation of norbornene gave exo- and endo-epoxide. The effect of surfactants supports the involvement of carbocation intermediates. The epoxidation of cyclic olefins follows the reactivity order cyclo-octene > norbornene > cyclopentene > cycloheptene > cyclohexene. Spectral studies suggest that oxo ruthenium (V) is the active oxidizing species." @default.
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- W2034303887 date "1992-01-01" @default.
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- W2034303887 title "Oxidation of alkenes using the RuCl3/PhIO system" @default.
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