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- W2034304046 abstract "The cathodic behaviour of zinc in 0.5 M Na2So4 aerated solution has been investigated using a rotating disc electrode. Since the steady-state current-voltage curves exhibit two well-separated diffusion plateaux, both steady-state (diffusion current vs. the disc angular velocity plts) and transient (frequency analysis of the electrohydrodynamical impedance) measurements which specifically sample mass-transport phenomena, have been carried out. It is shown that, in the vicinity of the corrosion potential (first plateau region) the dissolved oxygen reduction occures through a layer of dissolution products whereas the electrode surface appears quasi-uniformly active at the second plateau. Electrochemical impedance measurements corroborate the existence of the layer and allow us to justify the shape of the entire current-voltage curve. Finally, additional experiments have been carried out in order to gain a better understanding of the nature and the properties of the layer." @default.
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- W2034304046 date "1984-12-01" @default.
- W2034304046 modified "2023-10-03" @default.
- W2034304046 title "The cathodic mass transport process during zinc corrosion in neutral aerated sodium sulphate solutions" @default.
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- W2034304046 doi "https://doi.org/10.1016/0368-1874(84)83624-2" @default.
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