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• W2034304291 abstract "The ammosamides A-C are chlorinated pyrrolo[4,3,2-de]quinoline metabolites isolated from the marine-derived Streptomyces strain CNR-698. The natural products, which possess a dense array of heteroatoms, were synthesized in 17-19 steps from 4-chloroisatin. That the five nitrogen atoms were introduced at the appropriate time and in a suitable oxidation state was key to the success of the total synthesis. Compared to synthetic deschloro ammosamide B, natural ammosamide B is much less susceptible to oxidative degradation." @default.
• W2034304291 created "2016-06-24" @default.
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• W2034304291 date "2010-02-04" @default.
• W2034304291 modified "2023-09-30" @default.
• W2034304291 title "Total Synthesis of the Ammosamides" @default.
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• W2034304291 doi "https://doi.org/10.1021/ja9106572" @default.
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