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• W2034312013 abstract "Four nickel complexes each containing an R-2,2′-dipicolylamine ligand species (RDPA; R = benzyl, isopropyl, or tert-butyl) were synthesized and structurally characterized. In the absence of an interfering coordinating counterion, BzDPA and iPrDPA form 1:2 nickel:ligand complexes, with two facial ligands completing an pseudooctahedral nickel(II) coordination environment. In contrast, the sterically hindered tBuDPA ligand instead forms 1:1 metal:ligand complexes, even in the absence of associating counterions. Two novel tBuDPA nickel complexes with different counterions are described: nickel(II) chloride gives rise to an unusual 2Ni–3Cl dimer complex, while nickel(II) nitrate affords a 1:1 nickel:ligand complex which crystallizes with both fac and mer conformations in the same unit cell." @default.
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• W2034312013 date "2010-03-01" @default.
• W2034312013 modified "2023-09-27" @default.
• W2034312013 title "Steric and counterion effects on the structure of dipicolylamine nickel complexes" @default.
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• W2034312013 doi "https://doi.org/10.1016/j.ica.2009.12.041" @default.
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