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- W2034313151 abstract "The incorporation of solvent lead ions in LPE grown garnet layers is investigated by means of film misfit measurements and EPMA in dependence on growth conditions. It is shown that the lead incorporation is essentially due to kinetical effects rather than the consequence of thermodynamic equilibrium. In particular, the lead content increases rapidly with the growth rate according to a linear function. The temperature dependence of the ascent of this function can be described by an Arrhenius law. It is shown that trapping models being in common use fail in explaining the results whereas a reasonable description can be achieved within the frame of an alternative trapping theory based on the SOS-lattice model. Der Einbau von Bleiionen des Lösungsmittels in LPE-Granatschichten wird in Abhängigkeit von den Wachstumsbedingungen mit Hilfe von Misfitmessungen und EPMA untersucht. Es wird gezeigt, daß der Bleieinbau im wesentlichen durch kinetische Effekte verursacht wird. Insbesondere steigt der Bleigehalt linear mit der Wachstumsrate an. Die Temperaturabhängigkeit dieses Anstieges kann mit einem Arrheniusgesetz beschrieben werden. Es wird gefunden, daß die üblich verwendeten Trappingmodelle die Ergebnisse nicht erklären können. Eine vernünftige Beschreibung der Resultate ist dagegen mit einer alternativen Trappingtheorie möglich, welche auf dem SOS-Gittermodell basiert." @default.
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- W2034313151 date "1987-12-16" @default.
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- W2034313151 title "Kinetic Segregation of Lead Impurities in Garnet LPE Films" @default.
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- W2034313151 doi "https://doi.org/10.1002/pssa.2211040229" @default.
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