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- W2034320827 abstract "Abstract Structural studies of newly synthesized substituted spirans, derived from methyl- and tert-butylbenzenes, containing either 1,5-dioxepine or 1,5-dithiepine system are reported. Crystal structures of two representative compounds were determined by X-ray diffraction. One of spirans containing 1,5-benzodithiepine appears in two isomeric forms equivalent by inversion of both spirorings. Energy calculations were carried out to find the preferred conformations. For spiran with sulfur atoms, the minimum-energy conformation is virtually identical with that in the solid state, whereas for the 1,5-dioxepine system they are different." @default.
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- W2034320827 date "2004-01-01" @default.
- W2034320827 modified "2023-09-27" @default.
- W2034320827 title "The structure of substituted spirans derived from benzo-1,5-dithiepine and benzo-1,5-dioxepine systems. Ring-reversal isomers" @default.
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- W2034320827 doi "https://doi.org/10.1016/j.molstruc.2003.09.011" @default.
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