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- W2034328078 abstract "The shielding effect of surrounding arms and chains on the encounter probability of reactive sites located both at the end of a linear chain and at several positions along the arms of star-branched chains with up to six arms is calculated by means of exact enumeration of samples prepared by Monte Carlo simulation. The changes of parameters that characterize the size and the shape of chain configurations during the approach of reactive centers located at the end of the linear chain and at the center of the star are evaluated. In addition to this specific case, which represents the central reaction step in reversible addition-fragmentation chain transfer star polymerization following the Z-group approach, a general discussion is given on the chain-length dependence of shielding factors associated with distinct segment positions." @default.
- W2034328078 created "2016-06-24" @default.
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- W2034328078 date "2007-10-28" @default.
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- W2034328078 title "Shielding effects in polymer-polymer reactions. II. Reactions between linear and star-branched chains with up to six arms" @default.
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- W2034328078 doi "https://doi.org/10.1063/1.2780167" @default.
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