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• W2034329145 endingPage "1991" @default.
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• W2034329145 abstract "Lithium intercalation into the oxide slabs of the cation-deficient n = 2 Ruddlesden−Popper oxysulfide Y2Ti2O5S2 to produce LixY2Ti2O5S2 (0 < x < 2) is described. Neutron powder diffraction measurements reveal that at low levels of lithium intercalation into Y2Ti2O5S2, the tetragonal symmetry of the host is retained: Li0.30(5)Y2Ti2O5S2, I4/mmm, a = 3.80002(2) Å, c = 22.6396(2) Å, Z = 2. The lithium ion occupies a site coordinated by four oxide ions in an approximately square planar geometry in the perovskite-like oxide slabs of the structure. At higher levels of lithium intercalation, the symmetry of the cell is lowered to orthorhombic: Li0.99(5)Y2Ti2O5S2, Immm, a = 3.82697(3) Å, b = 3.91378(3) Å, c = 22.2718(2) Å, Z = 2, with ordering of Li+ ions over two inequivalent sites. At still higher levels of lithium intercalation, tetragonal symmetry is regained: Li1.52(5)Y2Ti2O5S2, I4/mmm, a = 3.91443(4) Å, c = 22.0669(3) Å, Z = 2. A phase gap exists close to the transition from the tetragonal to orthorhombic structures (0.6 < x < 0.8). The changes in symmetry of the system with electron count may be considered analogous to a cooperative electronically driven Jahn−Teller type distortion. Magnetic susceptibility and resistivity measurements are consistent with metallic properties for x > 1, and the two-phase region is identified as coincident with an insulator to metal transition." @default.
• W2034329145 created "2016-06-24" @default.
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• W2034329145 date "2004-01-31" @default.
• W2034329145 modified "2023-10-12" @default.
• W2034329145 title "Electronically Driven Structural Distortions in Lithium Intercalates of the <i>n </i>= 2 Ruddlesden−Popper-Type Host Y₂Ti₂O₅S₂: Synthesis, Structure, and Properties of Li<i>_x</i>Y₂Ti₂O₅S₂ (0 < <i>x</i> < 2)" @default.
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• W2034329145 doi "https://doi.org/10.1021/ja037763h" @default.
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