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• W2034330921 startingPage "8475" @default.
• W2034330921 abstract "Electronic structures of metallic ${mathrm{LaNiO}}_{3}$ and insulating ${mathrm{NdNiO}}_{3}$ are investigated using electron spectroscopies as well as band-structure and model-Hamiltonian calculations. It is shown that there is an increase in the transfer integral, ${mathit{t}}_{mathit{p}mathit{d}}$ in ${mathrm{LaNiO}}_{3}$ compared to ${mathrm{NdNiO}}_{3}$ though ${mathit{U}}_{mathit{d}mathit{d}}$ and ensuremath{Delta} are very similar. A phase diagram obtained with a multiband Hubbard model explains the metal-insulator transition as well as the anomalous resistivity of ${mathrm{NdNiO}}_{3}$ under pressure while indicating various interesting possibilities near the metal-insulator phase line." @default.
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• W2034330921 date "1994-03-15" @default.
• W2034330921 modified "2023-09-26" @default.
• W2034330921 title "Covalency-driven unusual metal-insulator transition in nickelates" @default.
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• W2034330921 doi "https://doi.org/10.1103/physrevb.49.8475" @default.
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