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• W2034332607 abstract "VUV light of 118.2 nm (10.49 eV) is produced by frequency tripling the third harmonic of a Nd: YAG laser (354.6 nm) in a Xe cell. With these photons time-of-flight mass spectra of n-hexane, 3-methylpentane, 2,2-dimethylbutane, 2,3-dimethylbutane and cyclohexane are obtained by single photon ionization. The simple set-up for production of 118.2 nm photons, the necessity of separating the 354.6 nm photons and the obtained mass spectra are discussed. The fragmentation of hexane as a function of its temperature is compared with the predictions from quasi-equilibrium theory. The model shows that for n-hexane less than 50% of the difference between photon energy and ionization energy is deposited in the molecular ion." @default.
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• W2034332607 date "1991-08-01" @default.
• W2034332607 modified "2023-09-25" @default.
• W2034332607 title "Laser single photon ionization mass spectrometry of linear, branched and cyclic hexanes" @default.
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• W2034332607 doi "https://doi.org/10.1016/0168-1176(91)80042-l" @default.
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