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- W2034333010 abstract "Displacement of η6-arene in (C6F5)2Co(η6-toluene), (Cl3Si)2Ni(η6-toluene), and (F3Si)2Ni(η6-toluene) by CO yielded very labile (C6F5)2Co(CO)3, (Cl3Si)2Ni(CO)3, and (F3Si)2Ni(CO)3, which are rare examples of isolated, characterized, simple carbonyl complexes of cobalt(II) and nickel(II). According to infrared ν(CO) studies the cobalt(II) tricarbonyl and the nickel(II) tricarbonyl derivatives are trigonal bipyramidal with the CO ligands in the axial positions. These η6-arene substitutions with CO are reversible under mild conditions. However, the cobalt system slowly degrades to cobalt(I) while the nickel system degrades to nickel(0) carbonyl compounds." @default.
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- W2034333010 date "1983-12-01" @default.
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- W2034333010 title "Carbonyl compounds of cobalt(II) and nickel(II). Reversible arene-carbon monoxide exchange and similarities to analogous η6-arene complexes" @default.
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- W2034333010 doi "https://doi.org/10.1016/0022-328x(83)87184-8" @default.
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