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- W2034333629 abstract "The solutions of malachite green leucocyanide (MGCN) in methanol, n-propanol and 2-propanol were investigated using pulse radiolysis. In the presence of oxygen, MG+-carbonium ions were radiolytically formed in two different time steps. The yield of MG+ in the slower process was dependent on oxygen concentration and was proportional to the yield of intermediate MG· radicals. The yield of MG· was about ten times higher in 2-propanol than in methanol and n-propanol solutions. The reactants responsible for MG· oxidation to MG+ were RO·2, hydroxyalkylperoxyl radicals derived from alcohols. The rate constant for MG· reaction with RO·2 were estimated as (6.5±1) × 108 M−1 s−1. The molar extinction coefficient of MG· was calculated as ϵ(400 nm) = (8.5±1) × 104 M−1 cm−1." @default.
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- W2034333629 date "1992-04-01" @default.
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- W2034333629 title "Pulse radiolysis of malachite green leucocyanide in alcoholic solvents, the influence of oxygen" @default.
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- W2034333629 doi "https://doi.org/10.1016/1359-0197(92)90247-d" @default.
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