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• W2034335896 abstract "Abstract Reverse electrodialysis (RED) is a process that can capture electrical energy from salinity gradients between seawater and river water through permselective ion exchange membranes. As ion exchange membranes are a key element in a RED system, enhancing their electrochemical characteristics is critical to maximizing system power performance. This study presents the preparation of porous nanocomposite cation exchange membranes via a two-step phase inversion technique. The phase inversion process controlled the structural variation (porosity) of the polymeric membranes in the presence of functionalized iron (III) oxide (Fe 2 O 3 –SO 4 2− ), which subsequently led to significantly improved electrochemical performance. A porous nanocomposite membrane containing an optimal amount of Fe 2 O 3 –SO 4 2− (0.7 wt%) at a thickness of 30 µm performed best, as it had an area resistance of 0.82 Ω cm 2 and a permselectivity of 85.6%. Application of this membrane in a RED system achieved gross power density of up to 1.4 W m −2 , which exceeds the power density obtained with the commercially available CSO (Selemion TM , Japan) membranes. Thus, effective design of ion exchange membranes through structure optimization increases the feasibility of salinity gradient power generation by RED." @default.
• W2034335896 created "2016-06-24" @default.
• W2034335896 creator A5031439227 @default.
• W2034335896 creator A5068327587 @default.
• W2034335896 date "2015-01-01" @default.
• W2034335896 modified "2023-09-24" @default.
• W2034335896 title "Evaluation of electrochemical properties and reverse electrodialysis performance for porous cation exchange membranes with sulfate-functionalized iron oxide" @default.
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• W2034335896 doi "https://doi.org/10.1016/j.memsci.2014.09.012" @default.
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