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- W2034338545 abstract "A number of products including apocarotenal, epoxycarotenal, apocarotenone, and epoxycarotenone generated by lipoxygenase (LOX) catalyzed co-oxidation of beta-carotene have been tentatively identified through the use of GC/MS and HPLC combined with photodiode array detection. Because of the large number of high molecular weight products detected and their probable chemical structures, a co-oxidation mechanism is proposed that involves random attack along the alkene chain of the carotenoid by a LOX-generated linoleoylperoxyl radical. It is suggested that a direct release from the enzyme of the radical, which initiates the co-oxidation of beta-carotene, is greater for pea LOX-3 than for pea LOX-2 or soybean LOX-1. It is proposed that further products may be formed by free radical propagated reactions and that the formation of 1,10- and 1,14-dicarbonyl compounds may arise by secondary oxidation of the primary products." @default.
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- W2034338545 date "1999-11-09" @default.
- W2034338545 modified "2023-09-25" @default.
- W2034338545 title "Co-oxidation of β-Carotene Catalyzed by Soybean and Recombinant Pea Lipoxygenases" @default.
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- W2034338545 doi "https://doi.org/10.1021/jf9901690" @default.
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