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- W2034340100 abstract "A kinetic study of the aluminium ion-assisted aquation of CoF(NH3)52+ was carried out. The pseudo-first order rate constant obtained can be expressed as kobsd=kAl[Al3+], where kAl=(1.6±0.2)×10−3 dm3 mol−1 s−1(I=2.0 mol dm−3, 25 °C). The reaction rate is independent of the pH in the (pH)obsd<3.3 range, in contrast with the pH-dependent rate for the CrF(NH3)52+-Al3+ system. The different behavior between CoF(NH3)52+ and CrF(NH3)52+ in aquation can be explained in terms of their electronic structures, as calculated on the basis of the CNDO/2 method." @default.
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- W2034340100 date "1981-06-01" @default.
- W2034340100 modified "2023-10-16" @default.
- W2034340100 title "The Aluminium Ion-assisted Aquation of [CoF(NH<sub>3</sub>)<sub>5</sub>]<sup>2+</sup>" @default.
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- W2034340100 doi "https://doi.org/10.1246/bcsj.54.1818" @default.
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