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- W2034342600 abstract "The 22 conceivable regioisomers of isoxazolo-fullerenes are listed, combined with a proposed nomenclature for their addition patterns. Two of them (I∗(mm2), I∗(2m)) are impossible on sterical hindrance. The twofold cycloaddition of 2,4,6-trimethoxy-benzonitrile oxide to [60]fullerene yields in a complex mixture of bisadducts 1. By combined HPLC separations, we isolated 11 fractions, which are distinguishable in their NMR spectra. From comparison of the possible symmetries for isoxazolo-fullerenes and from the spectra of the isolated reaction products 1 can be concluded that some fractions contain two bisadducts. In the end our analytical data corresponds to 16 bisadducts of 20 possible ones." @default.
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- W2034342600 date "1999-08-01" @default.
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- W2034342600 title "Twofold cycloaddition of 2,4,6-trimethoxy-benzonitrile oxide to [60]fullerene" @default.
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- W2034342600 doi "https://doi.org/10.1016/s0040-4020(99)00606-7" @default.
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