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- W2034342608 abstract "An efficient protocol of the Ir-catalyzed allylic substitution reaction is reported using N,O-bis(trimethylsilyl)acetamide as a base in the presence of nBu4NF as a cocatalyst. The reaction completely proceeded under very mild conditions, and a branched allylated compound that is not easy to access via the Tsuji-Trost reaction can be synthesized. The reaction system is practical enough to be applicable for polymer syntheses. The Ir- and Pd-catalyzed allylation polycondensations generally show complementary regio- and stereoselectivities. The Ir-catalyzed reaction is versatile, and a mixed dual regioselectivity such as a branched-linear selectivity on each electrophile can also be achieved." @default.
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- W2034342608 date "2008-01-01" @default.
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- W2034342608 title "An Efficient Protocol of Iridium-Catalyzed Allylic Substitution Reaction and Its Application to Polymer Synthesis: Complementary Regio- and Stereoselective Allylation Polycondensation via Ir and Pd Catalyses" @default.
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- W2034342608 doi "https://doi.org/10.1021/ja076019k" @default.
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