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• W2034342617 startingPage "7473" @default.
• W2034342617 abstract "Abstract Donor–bridge–acceptor triad (Por‐2TV‐C 60 ) and tetrad molecules ((Por) 2 ‐2TV‐C 60 ), which incorporated C 60 and one or two porphyrin molecules that were covalently linked through a phenylethynyl‐oligothienylenevinylene bridge, were synthesized. Their photodynamics were investigated by fluorescence measurements, and by femto‐ and nanosecond laser flash photolysis. First, photoinduced energy transfer from the porphyrin to the C 60 moiety occurred rather than electron transfer, followed by electron transfer from the oligothienylenevinylene to the singlet excited state of the C 60 moiety to produce the radical cation of oligothienylenevinylene and the radical anion of C 60 . Then, back‐electron transfer occurred to afford the triplet excited state of the oligothienylenevinylene moiety rather than the ground state. Thus, the porphyrin units in (Por)‐2TV‐C 60 and (Por) 2 ‐2TV‐C 60 acted as efficient photosensitizers for the charge separation between oligothienylenevinylene and C 60 ." @default.
• W2034342617 created "2016-06-24" @default.
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• W2034342617 date "2012-05-03" @default.
• W2034342617 modified "2023-10-07" @default.
• W2034342617 title "Photoinduced Energy and Electron Transfer in Phenylethynyl‐Bridged Zinc Porphyrin–Oligothienylenevinylene–C ₆₀ Ensembles" @default.
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• W2034342617 doi "https://doi.org/10.1002/chem.201102260" @default.
• W2034342617 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22556056" @default.
• W2034342617 hasPublicationYear "2012" @default.
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