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- W2034347812 endingPage "3519" @default.
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- W2034347812 abstract "Several thallium(III) porphyrin complexes [Tl(por)X] with the axial ligand x = MeCO2, CF3CO2, Cl, Br, l, CN, SCN or N3, have been obtained via ligand-exchange reactions from the corresponding thallium(III) trifluoroacetates. All compounds were characterized by 1H NMR, UV/VIS spectroscopy, and elemental analysis. Fourteen compounds were investigated in detail by X-ray crystallography to obtain information on the influence of the axial ligand on the macrocycle core conformation in main-group metalloporphyrins and to establish the molecular stereochemistry of thallium(III) porphyrins with cyano, acetato, thiocyanato, bromo, iodo and azido groups as axial ligands." @default.
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- W2034347812 date "1993-01-01" @default.
- W2034347812 modified "2023-10-18" @default.
- W2034347812 title "Synthesis and characterization of halogeno- and pseudo-halogeno-thallium(III) porphyrin complexes. Variation of the co-ordination geometry as a function of the axial ligand" @default.
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