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• W2034348459 abstract "Five model compounds of cytochrome P-450, [Fe(III)(porphyrin)(thiolate)] (high spin) and two model compounds of cytochrome c, [Fe(III)(TPP)(thioether)2]ClO4 (low spin) have been prepared, and their far-infrared spectra measured to assign the axial FeS stretching vibrations. Based on 54Fe56Fe isotope shift data, the Fe- S− (thiolate) and FeS0 (thioether) stretching vibrations have been assigned at 345−335 and 333−323 cm−1, respectively. The [Fe(TPP)(SC6H5)2]− ion (low spin) exhibits the anti-symmetric S−FeS− stretching band at 345 cm−1 which is about 20 ∼ 16 cm−1 higher than the S0Fe%z.sbnd;S0 stretching vibration of the [Fe(TPP)-(thioether)2]+ ion. This result is interpreted as indicating that the FeS− bond is stronger than the S0z.sbnd;FeS0 bond if other conditions are equal. Possible origins of frequency discrepancy between cytochrome P-450cam (351 cm−1 and its model compounds have been discussed, and the failure to observe the FeS vibrations in Raman spectra has been attributed to the small oscillator strength of the FeS CT transition in the UV region." @default.
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• W2034348459 date "1985-01-01" @default.
• W2034348459 modified "2023-10-18" @default.
• W2034348459 title "Ironsulfur vibrations in model compounds of cytochromes P-450 and c" @default.
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• W2034348459 doi "https://doi.org/10.1016/s0020-1693(00)93738-1" @default.
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