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- W2034356209 abstract "Abstract 2-(Mercaptobenzothiazolyl)ethyl vinyl ether (TVE), 2-mercaptobenzoxazolyl)ethyl vinyl ether (OVE), and 2-(mercaptobenzimidazolyl)ethyl vinyl ether (IVE) were prepared from the reactions of the respective mercaptobenzazoles with chloroethyl vinyl ether. These monomers homopolymerized with cationic initiator to give relatively low molecular weight resinous materials, but radical initiator gave no polymer. The radical copolymerizations with vinyl chloride (VC) as M1 were performed, and the colorless copolymers were obtained when the VC contents were more than ca. 50 mole %. The monomer reactivity ratios and Q, e values were determined as follows: TVE (M2)-VC: r1 = 2.02, r2 = 0.164, Q2 = 0.02, e2 = -1.85, OVE(M2)-VC: r1 = 1.65, r2 = 0.134, Q2 = 0.02, e2 = -2.03, IVE(M2)-VC: r1 = 0.05, r2 = 14.0, Q2 = 0.04, e2 = -0.20. These copolymers were less thermally stable than, the ordinary PVC. These monomers could easily undergo alternating copolymerization with maleic anhydride." @default.
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- W2034356209 date "1980-08-01" @default.
- W2034356209 modified "2023-10-16" @default.
- W2034356209 title "Sulfur-Containing Vinyl Monomers. XVII. Preparation and Polymerization of 2-(Mercaptobenzazolyl)ethyl Vinyl Ethers" @default.
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- W2034356209 doi "https://doi.org/10.1080/00222338008068116" @default.
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