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- W2034361036 abstract "A theory for ionic conductance which assumes that the equilibrium between the central ion and its ionic atmosphere is not appreciably distorted by the application of the external field is proposed. On the basis of this approach, values of the radii for the individual ion are obtained by the extrapolation of conductance and transference data to infinite dilution. These values of the radii when inserted into the equations resulting from the theory yield expressions for conductance and transference that very closely follow the experimental ones up to 0.02M. Even at concentrations as high as molar, the discrepancy between the equilibrium theory and experiment is not large. The values of the ionic radii obtained from the theory are also correlated with the corresponding values of equivalent conductances at infinite dilution. The larger the ion, the more closely does it appear to obey the laws of classical hydrodynamics. For smaller ions, deviations from classical hydrodynamics increase rapidly as the radius decreases. On this basis, the high conductance of hydronium ion appears to follow naturally from the small radius obtained, namely, 0.95A. Furthermore, the deviation from the classical theory appears to be given by an expression involving the size of the hole that the ion must make in order to jump from equilibrium position to equilibrium position in the solvent, an idea suggested by the modern theory of liquids as developed by Eyring and his collaborator." @default.
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- W2034361036 date "1939-06-01" @default.
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- W2034361036 title "An Equilibrium Theory of Ionic Conductance" @default.
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