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- W2034366251 abstract "We report on the crystallographic structure of the layered perovskite iridate Sr3Ir2O7, investigated using transmission electron microscopy. The space group was found to be Bbcb (D2h22, No. 68 in the International Tables for Crystallography) at 315 K. A very fine twin structure with 90° rotation with respect to the c-axis was observed. The crystal structure at temperatures lower than 285 K, where a phase transition from paramagnetism to weak ferromagnetism is known to occur, was also examined. There was no difference in the extinction rule for the diffraction patterns between the two phases. We conclude that there is no change in the space group for this magnetic transition. There still remains the possibility of a change in the rotation angle of IrO6 octahedrons and a corresponding change in the interatomic distance between Ir and O, though." @default.
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- W2034366251 date "2004-10-01" @default.
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- W2034366251 title "Crystal structure of Sr3Ir2O7 investigated by transmission electron microscopy" @default.
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- W2034366251 doi "https://doi.org/10.1016/j.jssc.2004.06.056" @default.
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