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• W2034376066 endingPage "69" @default.
• W2034376066 startingPage "62" @default.
• W2034376066 abstract "The risk assessment of groundwater pollution by pesticides may be based on pesticide sorption and biodegradation kinetic parameters estimated with inverse modeling of datasets from either batch or continuous flow soil column experiments. In the present work, a chemical non-equilibrium and non-linear 2-site sorption model is incorporated into solute transport models to invert the datasets of batch and soil column experiments, and estimate the kinetic sorption parameters for two pesticides: N-phosphonomethyl glycine (glyphosate) and 2,4-dichlorophenoxy-acetic acid (2,4-D). When coupling the 2-site sorption model with the 2-region transport model, except of the kinetic sorption parameters, the soil column datasets enable us to estimate the mass-transfer coefficients associated with solute diffusion between mobile and immobile regions. In order to improve the reliability of models and kinetic parameter values, a stepwise strategy that combines batch and continuous flow tests with adequate true-to-the mechanism analytical of numerical models, and decouples the kinetics of purely reactive steps of sorption from physical mass-transfer processes is required." @default.
• W2034376066 created "2016-06-24" @default.
• W2034376066 creator A5019408992 @default.
• W2034376066 creator A5064600368 @default.
• W2034376066 creator A5064829938 @default.
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• W2034376066 date "2012-03-01" @default.
• W2034376066 modified "2023-09-26" @default.
• W2034376066 title "Combining experimental techniques with non-linear numerical models to assess the sorption of pesticides on soils" @default.
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• W2034376066 doi "https://doi.org/10.1016/j.jconhyd.2011.09.010" @default.
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• W2034376066 hasPublicationYear "2012" @default.
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