FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034377575> ?p ?o ?g. }

• W2034377575 endingPage "16023" @default.
• W2034377575 startingPage "16023" @default.
• W2034377575 abstract "A novel oxide-supported Ir dimer, which was found to be active for transfer hydrogenation of aromatic ketones, was prepared on a γ-Al2O3 surface from an Ir dimer complex [Ir2{η5-C5(CH3)5}2(μ-CH2)2] (Ir2) with an IrIr bond. Detailed characterization of the γ-Al2O3-supported Ir dimer (Ir2/γ-Al2O3) revealed that the structure of Ir2 consisted of an Ir dimer with an Ir–Ir bond attached to the γ-Al2O3 surface by two bridged Ir–(OAl)2–Ir bonds. The supported Ir2/γ-Al2O3 dimer with bridged Ir–(OAl)2–Ir bonds acted as an efficient catalyst for transfer hydrogenation (turnover number of acetophenone = 699 (24 h)), while homogeneous Ir2, SiO2- and MgO-supported Ir2 were much less active. A structural transformation at the interface of the Ir dimer and the γ-Al2O3 surface was suggested to assist the transfer hydrogenation catalysis via the formation of an Ir2–H2 species on the γ-Al2O3 surface (Ir2–H2/γ-Al2O3) as a key intermediate in the transfer hydrogenation. The present study deepened the understanding of the role and dynamic behaviour of the oxide surface in the hydrogen transfer catalysis on the supported Ir dimer." @default.
• W2034377575 created "2016-06-24" @default.
• W2034377575 creator A5000243080 @default.
• W2034377575 creator A5024171030 @default.
• W2034377575 creator A5028744891 @default.
• W2034377575 creator A5048183759 @default.
• W2034377575 creator A5057450613 @default.
• W2034377575 creator A5068469551 @default.
• W2034377575 creator A5083525533 @default.
• W2034377575 date "2012-01-01" @default.
• W2034377575 modified "2023-10-06" @default.
• W2034377575 title "Surface-assisted transfer hydrogenation catalysis on a γ-Al2O3-supported Ir dimer" @default.
• W2034377575 cites W1964060855 @default.
• W2034377575 cites W1964151831 @default.
• W2034377575 cites W1966377892 @default.
• W2034377575 cites W1970660769 @default.
• W2034377575 cites W1972299443 @default.
• W2034377575 cites W1973508433 @default.
• W2034377575 cites W1973904699 @default.
• W2034377575 cites W1978683745 @default.
• W2034377575 cites W1982767566 @default.
• W2034377575 cites W1990884132 @default.
• W2034377575 cites W2004621279 @default.
• W2034377575 cites W2013160605 @default.
• W2034377575 cites W2018222553 @default.
• W2034377575 cites W2026411825 @default.
• W2034377575 cites W2030606721 @default.
• W2034377575 cites W2031041705 @default.
• W2034377575 cites W2051118901 @default.
• W2034377575 cites W2053855843 @default.
• W2034377575 cites W2054973957 @default.
• W2034377575 cites W2055438639 @default.
• W2034377575 cites W2057352796 @default.
• W2034377575 cites W2068073342 @default.
• W2034377575 cites W2068617439 @default.
• W2034377575 cites W2070227796 @default.
• W2034377575 cites W2081936026 @default.
• W2034377575 cites W2082495643 @default.
• W2034377575 cites W2082663021 @default.
• W2034377575 cites W2084311144 @default.
• W2034377575 cites W2085359531 @default.
• W2034377575 cites W2085595472 @default.
• W2034377575 cites W2094642658 @default.
• W2034377575 cites W2095018307 @default.
• W2034377575 cites W2097629267 @default.
• W2034377575 cites W2106596502 @default.
• W2034377575 cites W2118786650 @default.
• W2034377575 cites W2120247726 @default.
• W2034377575 cites W2121396475 @default.
• W2034377575 cites W2125979718 @default.
• W2034377575 cites W2126364600 @default.
• W2034377575 cites W2126440684 @default.
• W2034377575 cites W2139098300 @default.
• W2034377575 cites W2143981217 @default.
• W2034377575 cites W2151971401 @default.
• W2034377575 cites W2152679587 @default.
• W2034377575 cites W2154881052 @default.
• W2034377575 cites W2154949549 @default.
• W2034377575 cites W2157871632 @default.
• W2034377575 cites W2159067923 @default.
• W2034377575 cites W2316825670 @default.
• W2034377575 cites W2320462534 @default.
• W2034377575 cites W2949138257 @default.
• W2034377575 cites W2949868451 @default.
• W2034377575 cites W2950882207 @default.
• W2034377575 cites W2951734757 @default.
• W2034377575 cites W4245779216 @default.
• W2034377575 doi "https://doi.org/10.1039/c2cp43106h" @default.
• W2034377575 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23104018" @default.
• W2034377575 hasPublicationYear "2012" @default.
• W2034377575 type Work @default.
• W2034377575 sameAs 2034377575 @default.
• W2034377575 citedByCount "17" @default.
• W2034377575 countsByYear W20343775752013 @default.
• W2034377575 countsByYear W20343775752014 @default.
• W2034377575 countsByYear W20343775752015 @default.
• W2034377575 countsByYear W20343775752016 @default.
• W2034377575 countsByYear W20343775752017 @default.
• W2034377575 countsByYear W20343775752018 @default.
• W2034377575 countsByYear W20343775752019 @default.
• W2034377575 countsByYear W20343775752022 @default.
• W2034377575 countsByYear W20343775752023 @default.
• W2034377575 crossrefType "journal-article" @default.
• W2034377575 hasAuthorship W2034377575A5000243080 @default.
• W2034377575 hasAuthorship W2034377575A5024171030 @default.
• W2034377575 hasAuthorship W2034377575A5028744891 @default.
• W2034377575 hasAuthorship W2034377575A5048183759 @default.
• W2034377575 hasAuthorship W2034377575A5057450613 @default.
• W2034377575 hasAuthorship W2034377575A5068469551 @default.
• W2034377575 hasAuthorship W2034377575A5083525533 @default.
• W2034377575 hasConcept C112887158 @default.
• W2034377575 hasConcept C153642686 @default.
• W2034377575 hasConcept C161790260 @default.
• W2034377575 hasConcept C178790620 @default.
• W2034377575 hasConcept C185592680 @default.
• W2034377575 hasConcept C2775888733 @default.
• W2034377575 hasConcept C2779546866 @default.
• W2034377575 hasConcept C2779851234 @default.

• next