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- W2034378197 abstract "α-Lithio N -alkylpyrrolidines and piperidines exhibit remarkable chemical and configurational stability. Based on comparisons of three related α-amino-organolithium classes and based on recent structural work from other laboratories, a hypothesis explaining the stability of these species is presented. Previous work in the area is reviewed. The search for configurationally stable α-amino carbanions has led to an interesting observation of differing reactivity of diastereomeric organolithiums and to the characterization of aracemic 2-lithio- N -methylpiperidine and 2-lithio- N -methylpyrrolidine as configurationally stable α-aminoorganolithiums. Details for the preparation of these and related α-lithioheterocycles, evaluation of their chemical and configurational stability, and a preliminary evaluation of the stereoselectivity of their reactions with electrophiles is presented." @default.
- W2034378197 created "2016-06-24" @default.
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- W2034378197 date "1994-01-01" @default.
- W2034378197 modified "2023-10-17" @default.
- W2034378197 title "Search for configurationally stable, aracemic α-amino organolithiums" @default.
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- W2034378197 doi "https://doi.org/10.1016/s0040-4020(01)90459-4" @default.
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