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- W2034379737 abstract "In 8-azapurines, the 1,2,3-triazole ring can assume three tautomeric forms. The corresponding 7-, 8- and 9- methy1-6-methylthio derivatives all underwent rapid thiohydrolysis to the respective 6-thio-8-azapurines, when treated with ammonium sulfide at room temperature. The high reactivity of the 8-methyl derivative was anticipated on the basis of its o-quinonoid structure. However, thiohydrolysis of 7- and 9- methyl-6-methylthio-8- azapurine is unexpected and contrasts sharply with the refractoriness of 7- and 9- methyl-6-methylthiopurine." @default.
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- W2034379737 date "1970-01-01" @default.
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- W2034379737 title "Thiohydrolysis of 6-Methylthio-8-Azapurines (7-Methylthio-1,2,3,4,6-Penta-Azaindenes) Bearing a Methyl Substituent in the Triazole Ring" @default.
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- W2034379737 doi "https://doi.org/10.1002/ijch.197000117" @default.
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