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- W2034380135 abstract "The isomerisation of 1,5-cyclooctadiene catalysed by Ir2H2Cl2(1,5-C8H12) (PPh3)2 under N2 occurs through consecutive reactions 1,5-C8H12 ⇌ 1,4-C8H12 → 1,3-C8H12; the first reaction is reversible whereas the second is irreversible. Under H2, a selective hydrogenation of the non-conjugated 1,5 and 1,4 isomers leads to cyclooctene. Mechanisms for the isomerization and hydrogenation are proposed." @default.
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- W2034380135 date "1975-01-01" @default.
- W2034380135 modified "2023-10-09" @default.
- W2034380135 title "Isomerisation and hydrogenation of 1,5-cyclooctadiene catalysed by Ir2H2Cl2(1,5-C8H12)(PPh3)2" @default.
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- W2034380135 doi "https://doi.org/10.1016/s0022-328x(00)91404-9" @default.
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