Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034382390> ?p ?o ?g. }
- W2034382390 endingPage "1408" @default.
- W2034382390 startingPage "1397" @default.
- W2034382390 abstract "The all-trans→13-cis⋅9-cis photoisomerization reaction of retinal in aerated nonpolar solvents has been studied by femtosecond time-resolved ultraviolet-visible (UV-VIS) absorption spectroscopy. The excited-state absorption spectra in the wavelength region 400–800 nm indicate that there is no all-trans→13-cis⋅9-cis isomerization reaction pathway that is complete in the electronic excited singlet manifold of S1, S2, and S3. The ground-state bleaching recovery of all-trans retinal monitored in the near UV (ultraviolet) wavelength region 310–390 nm shows that a perpendicular excited singlet state (p*) takes part in the all-trans→13-cis⋅9-cis isomerization reaction. The lifetime of p* is about 7 ps, and the precursor of p* is most probably the S2 state. The isomerization quantum yield derived from the femtosecond UV absorption data agrees well with those determined by the HPLC analysis of the photoproduct. The temperature dependence of the isomerization quantum yield indicates the existence of a potential-energy barrier as high as (1.2±0.6)×103 cm−1 on the reaction pathway from the S2 state to the p* state." @default.
- W2034382390 created "2016-06-24" @default.
- W2034382390 creator A5037767845 @default.
- W2034382390 creator A5045212371 @default.
- W2034382390 date "1998-07-22" @default.
- W2034382390 modified "2023-10-02" @default.
- W2034382390 title "Femtosecond ultraviolet-visible absorption study of all-trans→13-cis⋅9-cis photoisomerization of retinal" @default.
- W2034382390 cites W1966000765 @default.
- W2034382390 cites W1966215370 @default.
- W2034382390 cites W1976204889 @default.
- W2034382390 cites W1987220293 @default.
- W2034382390 cites W1988770469 @default.
- W2034382390 cites W1991789701 @default.
- W2034382390 cites W1994427899 @default.
- W2034382390 cites W1994530500 @default.
- W2034382390 cites W1996118742 @default.
- W2034382390 cites W2001926462 @default.
- W2034382390 cites W2002691643 @default.
- W2034382390 cites W2003754330 @default.
- W2034382390 cites W2004594170 @default.
- W2034382390 cites W2005717744 @default.
- W2034382390 cites W2007395682 @default.
- W2034382390 cites W2009536780 @default.
- W2034382390 cites W2014290285 @default.
- W2034382390 cites W2015603085 @default.
- W2034382390 cites W2021167563 @default.
- W2034382390 cites W2023940054 @default.
- W2034382390 cites W2024722510 @default.
- W2034382390 cites W2030647638 @default.
- W2034382390 cites W2031487394 @default.
- W2034382390 cites W2038956169 @default.
- W2034382390 cites W2041438119 @default.
- W2034382390 cites W2043614335 @default.
- W2034382390 cites W2045887879 @default.
- W2034382390 cites W2047343368 @default.
- W2034382390 cites W2047490144 @default.
- W2034382390 cites W2049880345 @default.
- W2034382390 cites W2051630418 @default.
- W2034382390 cites W2056238750 @default.
- W2034382390 cites W2065120242 @default.
- W2034382390 cites W2066513229 @default.
- W2034382390 cites W2074293030 @default.
- W2034382390 cites W2076186891 @default.
- W2034382390 cites W2076736912 @default.
- W2034382390 cites W2081071394 @default.
- W2034382390 cites W2085893705 @default.
- W2034382390 cites W2090681980 @default.
- W2034382390 cites W2091181737 @default.
- W2034382390 cites W2093234852 @default.
- W2034382390 cites W2126241024 @default.
- W2034382390 cites W2127929872 @default.
- W2034382390 cites W2154854029 @default.
- W2034382390 cites W2950065583 @default.
- W2034382390 cites W2951367808 @default.
- W2034382390 cites W2952953504 @default.
- W2034382390 cites W3004918820 @default.
- W2034382390 doi "https://doi.org/10.1063/1.476692" @default.
- W2034382390 hasPublicationYear "1998" @default.
- W2034382390 type Work @default.
- W2034382390 sameAs 2034382390 @default.
- W2034382390 citedByCount "56" @default.
- W2034382390 countsByYear W20343823902012 @default.
- W2034382390 countsByYear W20343823902013 @default.
- W2034382390 countsByYear W20343823902014 @default.
- W2034382390 countsByYear W20343823902015 @default.
- W2034382390 countsByYear W20343823902016 @default.
- W2034382390 countsByYear W20343823902020 @default.
- W2034382390 countsByYear W20343823902021 @default.
- W2034382390 countsByYear W20343823902022 @default.
- W2034382390 countsByYear W20343823902023 @default.
- W2034382390 crossrefType "journal-article" @default.
- W2034382390 hasAuthorship W2034382390A5037767845 @default.
- W2034382390 hasAuthorship W2034382390A5045212371 @default.
- W2034382390 hasConcept C119824511 @default.
- W2034382390 hasConcept C120665830 @default.
- W2034382390 hasConcept C121332964 @default.
- W2034382390 hasConcept C125287762 @default.
- W2034382390 hasConcept C126661725 @default.
- W2034382390 hasConcept C159985019 @default.
- W2034382390 hasConcept C161790260 @default.
- W2034382390 hasConcept C167735695 @default.
- W2034382390 hasConcept C171001562 @default.
- W2034382390 hasConcept C178790620 @default.
- W2034382390 hasConcept C181500209 @default.
- W2034382390 hasConcept C184779094 @default.
- W2034382390 hasConcept C185592680 @default.
- W2034382390 hasConcept C192562407 @default.
- W2034382390 hasConcept C2776798109 @default.
- W2034382390 hasConcept C32891209 @default.
- W2034382390 hasConcept C33062035 @default.
- W2034382390 hasConcept C49040817 @default.
- W2034382390 hasConcept C520434653 @default.
- W2034382390 hasConcept C62520636 @default.
- W2034382390 hasConcept C75473681 @default.
- W2034382390 hasConcept C85311670 @default.
- W2034382390 hasConcept C91881484 @default.
- W2034382390 hasConcept C95503338 @default.
- W2034382390 hasConceptScore W2034382390C119824511 @default.